Kinetics of oxidation of nitrite by hypochlorite ions in aqueous basic solution
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Kinetics and Mechanism of Oxidation of Hydroxyurea with Hexacyano- ferrate(III) Ions in Aqueous Solution
Hydroxyurea (HU) effectively reduces Fe(CN)6 to Fe(CN)6 species in neutral and basic aqueous solution via an electron transfer process that includes the formation and subsequent fading out of a free radical, U (U ≡ H2N−C(=O)N(H)O). The EPR spectrum of U in H2O solutions suggests that the unpaired electron is located predominantly on the hydroxamate hydroxyl-oxygen atom. Visible spectrophotometr...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1976
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v76-488